Preparation of In-doped Y2O3 ceramics through a sol-gel process: Effects on the structural and electronic properties

The Pechini-type sol-gel (PSG) process has been used for the preparation of doped oxides due to its capability to overcome most of the difficulties that frequently occur by using other producing methods. In this work we analyze the case of samples of pure and In-doped yttria (Y₂O₃) prepared by the PSG process. We experimentally characterize the synthesized samples by x-ray diffraction, micro-Raman spectroscopy, electrochemical impedance spectroscopy (EIS), and time-differential perturbed γ-γ angular correlation (PAC) spectroscopy, and we compare these results with those obtained starting from commercial oxide powders. We found that the PSG process can be used to successfully produce doped yttria in the cubic phase, with the impurities substitutionally located at the cationic sites of the structure. By the proposed PSG route, the inclusion of impurities does not affect the particle size nor the resistivity. However, when we compare the PSG samples with other samples produced from commercial powder, we found that the first have lower resistivities at grain interiors. On the other hand, PAC spectroscopy in ¹¹¹In(→¹¹¹Cd)-doped yttria allows the study of the dynamic hyperfine interactions observed by the radioactive ¹¹¹Cd impurity-probe, which can be used to “sense” the host electron availability near the impurities after the electron-capture decay of ¹¹¹In. Differences between PAC spectra for PSG samples and the commercial powder suggest that the PSG process introduces additional donor defects into the yttria electronic structure, which is consistent with the lower resistivity observed in the PSG samples by EIS spectroscopy.     

社会主义核心价值观融入高职英语教学研究

在经济全球化、文化碰撞融合、价值多元化的开放时代,高职学生的价值观形成遇到挑战。社会主义核心价值观兼顾国家、社会、个人三个层面,是新时代中国发展、社会进步和个人发展的根本指针。高职英语课堂是中西文化交融的前沿阵地。为了培养有德行、有技能的新时代劳动者,最终实现“以德立人、以技立业”,高职英语课堂有责任融入社会主义核心价值观,将知识传授、技能培养与德育相结合。     

曙光煤矿1226综采工作面瓦斯抽采技术

采用综合应用理论分析、现场实测的方法,对山西汾西集团曙光煤矿1226高瓦斯综采工作面瓦斯来源进行了分析,提出并实施了分区段“风排+煤层钻孔抽放+裂隙带钻孔抽放”的联合瓦斯抽采技术。现场监测结果显示:1226综采工作面上隅角瓦斯浓度控制在0.45%~0.75%,回风流中瓦斯浓度控制在了0.44%~0.75%,瓦斯治理效果明显改善。     

Al2O3 loss prediction model of selective laser melting Al2O3–Al composite

The element/phase loss is undesirable but existing during selective laser melting (SLM) of materials with volatile element/phase, which not only changes the material composition but also affects the molten pool flow. In the previous researches, the effect of remelting on the element/phase loss was neglected during the SLM process, instead, laser energy density was thought to be uppermost. In fact, the SLM process fabricates the parts in a manner of line by line and layer by layer, i.e., additive character, and the remelting in the overlap zone occurs during the SLM process. In this paper, three different Al₂O₃ loss prediction models of SLM Al₂O₃–Al composite by considering the additive character of SLM and the distribution of the Al₂O₃ associated with the different molten pool driving forces were developed. By comparing with the experimental results and predicted results, it is found that the Al₂O₃ is distributed on both sides of the molten pool under the combined action of the Marangoni flow and the evaporation recoil pressure. This kind of Al₂O₃ distribution enhances the effect of the remelting on the Al₂O₃ loss, i.e., the remelting brings a logarithmic increase in the Al₂O₃ loss rate. This determines the final Al₂O₃ loss rate of the SLMed 3D samples. During this study, although the Al₂O₃ loss rate of the single-track is only 33%, the loss rate of SLMed 3D samples increases significantly to 97% when the hatching space of 60 μm and scanning speed of 200 mm/s are utilized, i.e., almost no Al₂O₃ in the 3D sample. Thus, it is more important to reduce the remelting, i.e., overlap rate for reducing the element/phase loss. This study is a benefit for understanding and reducing the element/phase loss in SLM.     

Microencapsulation of oil soluble polyaspartic acid ester and isophorone diisocyanate and their application in self-healing anticorrosive epoxy resin

Isocyanate and amine solution are microencapsulated, respectively, via in situ polymerization to realize the self-healing function in epoxy matrix. First, the isophorone diisocyanate (IPDI) microcapsules prepared with different core/shell ratios, emulsifier dosages and emulsification rates are characterized by field emission scanning electron microscope (FE-SEM). They exhibit integral spherical shape when the core/shell ratio is 3:1 and emulsifier concentration is 2.52 wt %, and the diameter of IPDI microcapsules ranged from 2.66 μm to 11.25 μm is manufactured by adjusting emulsification rate over the range of 3000–9000 rpm. Besides, during the microencapsulation of polyaspartic acid ester (PAE), urea, tung oil, as well as aqueous isocyanate are proposed to improve the stability of PAE emulsion. SEM and FTIR results reveal that aqueous isocyanate can react with partial PAE and form polyurea (PU) layer to take protection effectively. Further, IPDI-PAE dual microcapsules are incorporated into epoxy coatings, the self-healing and anticorrosion performance of coatings with various amounts of microcapsules are investigated systematically. It was found that the degree of repair and anticorrosion are increased with increasing microcapsules loading, and the appropriate amount of microcapsules addition is 15 wt %, which corresponding to 93% repair efficiency. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48478.     

Seeing is believing? When scanning electron microscopy (SEM) meets clinical dentistry: The replica technique.

In restorative dentistry, the in situ replication of intra‐oral situations, is based on a non‐invasive and non‐destructive scanning electron microscopy (SEM) evaluation method. The technique is suitable for investigation restorative materials and dental hard‐ and soft‐tissues, and its interfaces. Surface characteristics, integrity of interfaces (margins), or fracture analysis (chipping, cracks, etc.) with reliable resolution and under high magnification (from ×50 to ×5,000). Overall the current study aims to share detailed and reproducible information about the replica technique. Specific goals are: (a) to describe detailed each step involved in producing a replica of an intra‐oral situation, (b) to validate an integrated workflow based on a rational sequence from visual examination, to macrophotography and SEM analysis using the replica technique; (c) to present three clinical cases documented using the technique. A compilation of three clinical situations/cases were analyzed here by means the replica technique showing a wide range of possibilities that can be reached and explored with the described technique. This guidance document will contribute to a more accurate use of the replica technique and help researchers and clinicians to understand and identify issues related to restorative procedures under high magnification.     

In Silico Analysis and Experimental Validation of Active Compounds from Cichorium intybus L. Ameliorating Liver Injury

This study aimed at investigating the possible mechanisms of hepatic protective activity of Cichorium intybus L. (chicory) in acute liver injury. Pathological observation, reactive oxygen species (ROS) detection and measurements of biochemical indexes on mouse models proved hepatic protective effect of Cichorium intybus L. Identification of active compounds in Cichorium intybus L. was executed through several methods including ultra performance liquid chromatography/time of flight mass spectrometry (UPLC-TOF-MS). Similarity ensemble approach (SEA) docking, molecular modeling, molecular docking, and molecular dynamics (MD) simulation were applied in this study to explore possible mechanisms of the hepato-protective potential of Cichorium intybus L. We then analyzed the chemical composition of Cichorium intybus L., and found their key targets. Furthermore, in vitro cytological examination and western blot were used for validating the efficacy of the selected compounds. In silico analysis and western blot together demonstrated that selected compound 10 in Cichorium intybus L. targeted Akt-1 in hepatocytes. Besides, compound 13 targeted both caspase-1 and Akt-1. These small compounds may ameliorate liver injury by acting on their targets, which are related to apoptosis or autophagy. The conclusions above may shed light on the complex molecular mechanisms of Cichorium intybus L. acting on hepatocytes and ameliorating liver injury.     

复频电导技术在隧洞超前探水中的应用

围岩富水带是隧道超前预报最关注的问题，目前，多使用电磁方法来预报围岩的含水性，但受到场地条件限制，面临掌子面条件、金属机具干扰、三维波场定位等诸多困难，特别是掌子面前方100 m范围内围岩的含水性预报，在国内外都是一个新的高难课题。在研究了岩体电导率与电容率复频特性的基础上，结合巴基斯坦NJ-TBM引水隧洞工程，开发了复频电导探水(CFC)技术。该技术基于电磁波反射与相干原理，选用100 kHz～10 MHz频率范围，采用电偶极子发射与阵列接收方式和偏移成像技术，突破了隧道内场地条件的限制。依据1/4相干波长确定含水体的位置，相干能量确定含水量的大小。在巴基斯坦NJ-TBM隧洞超前探水的应用，证明了该方法的可行性与有效性。      

南海珊瑚岛礁水域浅层地震反射波勘探

在南海某珊瑚岛礁的工程勘察中，采用快速高效的浅层水域地震反射波勘探方法配合钻探进行联合勘察，将钻孔的“点”与物探的“线”结合起来，相互对比、佐证，进行综合解释，查明了岛礁珊瑚松散沉积物的厚度、基岩起伏形态及大范围内的连续地质剖面。勘探结果为岛礁岩土工程性状调查、水文地质调查以及工程建设提供了可靠的地质依据和设计参数，取得了理想的效果。水域地震反射波对岛礁的不同地貌单元内礁坪、向海坡、潟湖、外海的沉积层界面反映清晰，但在外礁坪区域由于现代海滩岩的发育，声波较难穿透。